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Corrosion and Prevention

Study the conditions for rusting and investigate various prevention methods

Chemistry of Rust

Equation

4Fe(s) + 3O₂(g) + 2nH₂O(l) → 2Fe₂O₃·nH₂O(s)

Conditions & Ionic Half Equations

Rusting requires water (H₂O) and oxygen (O₂).

Anode: Fe(s) → Fe²⁺(aq) + 2e⁻

Cathode: O₂(g) + 4H⁺(aq) + 4e⁻ → 2H₂O(l)

Formula

Fe₂O₃ · nH₂O

Full Name

Hydrated Iron(III) oxide

HKDSE Tip

  • Essential conditions:
    Both water (H₂O) and oxygen (O₂) are required for rusting.
  • Factors accelerating rusting:
    Soluble ionic substances (e.g. NaCl), acidic pollutants, high temperature, and scratches on the iron surface all speed up rusting.
  • Sacrificial protection:
    Connect iron to a more reactive metal (e.g. Zn, Mg). The more reactive metal loses electrons and corrodes instead of the iron.
  • Common protection methods:
    Cathodic protection, electroplating, tin-plating, plastic coating, oiling, and using stainless steel alloys can all slow down or prevent corrosion.

Lab Guide

  1. 1
    Choose Condition

    Select a control or a specific rusting/prevention condition.

  2. 2
    Observe Changes

    Observe color changes on the nail until it is fully rusted or the observation period ends.

  3. 3
    Understand Principle

    Read the explanation to understand why some conditions accelerate or prevent rusting.

Explanation

Please select a condition first