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Addition Polymerization

Visualize how monomers join to form long-chain polymers
Monomer Units:
Ethene

Monomer Structure

CCHHHH
Ethene

Polymer (Repeat Unit)

Chemical Equation

Addition polymerization: the C=C double bond breaks and monomers link by single bonds to form a long-chain polymer. No small-molecule by-product is formed.

Select Polymer

Common Uses

  • Plastic bags
  • Squeeze bottles

Environmental Issues

  • Non-biodegradable: Do not break down easily, causing pollution.
  • Harmful gases on combustion: e.g. PVC releases hydrogen chloride (HCl), a toxic and acidic gas that causes acid rain.
  • Burning PS can release toxic fumes and dense black smoke (unburnt carbon soot).